Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate
CAS: 1884137-92-1
Molecular Formula: C69H56BF24IrN2P
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate - Names and Identifiers
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate - Physico-chemical Properties
| Molecular Formula | C69H56BF24IrN2P |
| Molar Mass | 1603.18 |
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate - Introduction
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate) is an organic gold complex with the formula [(η5-C8H12)(PPhMe2)(μ-Cl)]Ir[(3,5-(CF3) κB-2C6C6H3). The following is a description of its nature, use, preparation and safety information:
Nature:
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate) is a gold complex with metal-organic coordination bonds. It has the appearance of a brown solid and is soluble in a variety of organic solvents. It is relatively stable in air and can be stored for a long time under inert atmosphere conditions.
Use:
The complex is often used as a catalyst, especially in catalytic reactions under an inert atmosphere. It has potential applications in asymmetric catalytic reactions, hydrogenation reactions, oxidation reactions and disproportionation reactions. Its application fields include organic synthesis, pharmaceutical chemistry and so on.
Preparation Method:
The method for preparing the complex is to coordinate 1,3-bis (2,4, 6-trimethylphenyl) imidazole and the ligand dimethylphenylphosphine ((CH3)2PPh) with iridium chloride and heptadiene in turn, and then add trifluoromethylphenylborate to obtain the complex.
Safety Information:
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate) is generally relatively safe under normal conditions of use. However, as an organometallic complex, it may still have certain risks, for example, irritation to the skin and eyes. Appropriate safety precautions should be taken during operation, including wearing protective glasses, gloves and laboratory coats. The use and handling of the complex should be carried out in a well-ventilated place. In all cases, proper laboratory procedures and safety precautions should be followed. If an accident occurs or there is any discomfort, you should seek medical help in a timely manner.
Nature:
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate) is a gold complex with metal-organic coordination bonds. It has the appearance of a brown solid and is soluble in a variety of organic solvents. It is relatively stable in air and can be stored for a long time under inert atmosphere conditions.
Use:
The complex is often used as a catalyst, especially in catalytic reactions under an inert atmosphere. It has potential applications in asymmetric catalytic reactions, hydrogenation reactions, oxidation reactions and disproportionation reactions. Its application fields include organic synthesis, pharmaceutical chemistry and so on.
Preparation Method:
The method for preparing the complex is to coordinate 1,3-bis (2,4, 6-trimethylphenyl) imidazole and the ligand dimethylphenylphosphine ((CH3)2PPh) with iridium chloride and heptadiene in turn, and then add trifluoromethylphenylborate to obtain the complex.
Safety Information:
Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate) is generally relatively safe under normal conditions of use. However, as an organometallic complex, it may still have certain risks, for example, irritation to the skin and eyes. Appropriate safety precautions should be taken during operation, including wearing protective glasses, gloves and laboratory coats. The use and handling of the complex should be carried out in a well-ventilated place. In all cases, proper laboratory procedures and safety precautions should be followed. If an accident occurs or there is any discomfort, you should seek medical help in a timely manner.
Last Update：2024-04-09 20:45:29
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Dimethylphenylphosphine(1,5-cyclooctadiene)[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate
(S)-BENZYL (4-(2-AMINO-3-METHYLBUTANAMIDO)CYCLOHEXYL)(CYCLOPROPYL)CARBAMATE
(7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid 2-oxo-2-phenylethyl ester
Μ-CONOTOXIN GIIIB
5-(4-CHLOROPHENYL)-2-[(3-CHLOROPHENYL)SULFANYL]NICOTINONITRILE
3-Cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester
Chromate,bis[2-hydroxy-5-nitro-3-[[2-oxo-1-[(phenylamino)carbonyl]propyl]azo]benzenesulfonato]-,compd. with 3-[(2-ethylhexyl)oxy]-1-propanamine
4-CHLORO-3-TRIFLUOROMETHYLPHENYL ISOTHIO
Chromat(2-), [2,4-Dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-2-hydroxy-5-nitrobenzolsulfonato(3-)]-, Dinatrium
Benzoic acid, 4-[(4-cyanobenzoyl)oxy]-3-methoxy-, 4-decylphenyl ester
(S)-BENZYL (4-(2-AMINO-3-METHYLBUTANAMIDO)CYCLOHEXYL)(CYCLOPROPYL)CARBAMATE
(7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid 2-oxo-2-phenylethyl ester
Μ-CONOTOXIN GIIIB
5-(4-CHLOROPHENYL)-2-[(3-CHLOROPHENYL)SULFANYL]NICOTINONITRILE
3-Cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester
Chromate,bis[2-hydroxy-5-nitro-3-[[2-oxo-1-[(phenylamino)carbonyl]propyl]azo]benzenesulfonato]-,compd. with 3-[(2-ethylhexyl)oxy]-1-propanamine
4-CHLORO-3-TRIFLUOROMETHYLPHENYL ISOTHIO
Chromat(2-), [2,4-Dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-2-hydroxy-5-nitrobenzolsulfonato(3-)]-, Dinatrium
Benzoic acid, 4-[(4-cyanobenzoyl)oxy]-3-methoxy-, 4-decylphenyl ester